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51.
高温固相反应合成了蓝色长余辉光致荧光材料CaAl2O4∶Eu2 ,Nd3 ,La3 ,激发后在暗室中观察,余辉的颜色为蓝色。进行了添加辅助激活剂的实验,首次在CaAl2O4∶Eu2 ,Nd3 中添加La3 。测定了该长余辉材料的激发光谱、发射光谱、余辉亮度和可视余辉时间,并对长余辉发光机理进行了探讨。余辉发射光谱的峰值波长为440nm,可视余辉时间达到18h以上。波长为280~380nm的光都可将该材料激发。实验结果表明,添加辅助激活剂La3 ,延长了CaAl2O4∶Eu2 ,Nd3 的可视余辉时间。在CaAl2O4∶Eu2 ,Nd3 ,La3 中,Eu2 是发光离子,Nd3 和La3 是辅助激活剂,发射光谱由Eu2 的激发态4f65d到基态4f7的电子跃迁产生。 相似文献
52.
The paper provides significant simplifications and extensions of results obtained by Gorsich, Genton, and Strang (J. Multivariate Anal. 80 (2002) 138) on the structure of spatial design matrices. These are the matrices implicitly defined by quadratic forms that arise naturally in modelling intrinsically stationary and isotropic spatial processes. We give concise structural formulae for these matrices, and simple generating functions for them. The generating functions provide formulae for the cumulants of the quadratic forms of interest when the process is Gaussian, second-order stationary and isotropic. We use these to study the statistical properties of the associated quadratic forms, in particular those of the classical variogram estimator, under several assumptions about the actual variogram. 相似文献
53.
P. Rudolf R. Raval P. Dumas G.P. Williams 《Applied Physics A: Materials Science & Processing》2002,75(1):147-153
Infrared (IR) spectroscopy of chemisorbed C60 on Ag (111), Au (110) and Cu (100) reveals that a non-IR-active mode becomes active upon adsorption, and that its frequency
shifts proportionally with the charge transferred from the metal to the molecule by about 5 cm-1 per electron. The temperature dependence of the frequency and the width of this IR feature have also been followed for C60/Cu (100) and were found to agree well with a weak anharmonic coupling (dephasing) to a low-frequency mode, which we suggest
to be the frustrated translational mode of the adsorbed molecules.
Additionally, the adsorption is accompanied by a broadband reflectance change, which is interpreted as due to the scattering
of conduction electrons of the metal surface by the adsorbate. The reflectance change allows determination of the friction
coefficient of the C60 molecules, which results in rather small values (∼2×109 s-1 for Ag and Au, and ∼1.6×109 s-1for Cu), consistent with a marked metallic character of the adsorbed molecules.
Pre-dosing of alkali atoms onto the metal substrates drastically changes the IR spectra recorded during subsequent C60 deposition: anti-absorption bands, as well as an increase of the broadband reflectance, occur and are interpreted as due
to strong electron–phonon coupling with induced surface states.
Received: 6 June 2001 / Accepted: 23 October 2001 / Published online: 3 April 2002 相似文献
54.
An experimental method for determining the real-time depth of laser-drilled holes is presented. The proposed method involves
detecting the laser-induced optoacoustic waves generated during the interaction of the laser beam with the material. Our optodynamic
study involved measuring the propagation times of these waves as they traveled through the material and analyzing their temporal
behavior during the drilling process. The experimental observations revealed an exponential relationship between the propagation
time of the longitudinal stress wave and the number of consecutive laser pulses.
Received: 25 October 2001 / Accepted: 27 October 2001 / Published online: 20 December 2001 相似文献
55.
The orientation-selective growth of LaNiO3 films on Si(100) by pulsed laser deposition using a MgO buffer 总被引:4,自引:0,他引:4
X.Y. Chen K.H. Wong C.L. Mak J.M. Liu X.B. Yin M. Wang Z.G. Liu 《Applied Physics A: Materials Science & Processing》2002,75(4):545-549
Highly (100)-oriented, (110)-oriented and polycrystalline LaNiO3 (LNO) films were successfully prepared on Si(100) using an oriented MgO film as a buffer. It was somewhat surprising to find
that that the orientation relation between the LNO film and the corresponding MgO buffer was: LNO(100)\MgO(110), LNO(110)\MgO(111)
and LNO(polycrystalline)\MgO(100). The crystalline quality of the LNO films was shown to be sensitive to the preparation conditions
of the MgO buffer. The film surface was very smooth, without micrometer-sized droplets being observed. All LNO films were
of metallic conductivity, with a room-temperature resistivities of approximately 250, 280 and 420 μΩ cm for the (110)-oriented,
(100)-oriented and polycrystalline LNO, respectively.
Received: 2 April 2001 / Accepted: 23 October 2001 / Published online: 3 June 2002 相似文献
56.
Nicolas Bergeron 《Mathematische Zeitschrift》2002,241(1):101-125
Let M be an arithmetic hyperbolic manifold and be a codimension 1 geodesic cycle. In this paper, we study the asymptotic growth of the -norm of the lifts of F in the congruence tower above M. We obtain an explicit value for the growth rate of this norm. In particular, we provide a new proof of a celebrated result
of Millson [Mi] on the homology of the arithmetic hyperbolic manifolds. The method is quite general and gives a new way of
getting non zero homology classes in certain locally symmetric spaces.
Received: 20 April 2001; in final form: 26 September 2001 / Published online: 28 February 2002 相似文献
57.
Patrick Dehornoy 《Algebra Universalis》2002,48(2):223-248
We solve the word problem of the identity x(yz) = (xy)(yz) by investigating a certain group describing the geometry of that identity. We also construct a concrete realization of the
one-generated free algebra relative to the above identity.
Received March 23, 2001; accepted in final form July 6, 2002. 相似文献
58.
Chuanming Zong 《Monatshefte für Mathematik》2002,134(3):247-255
In this article we study the simultaneous packing and covering constants of two-dimensional centrally symmetric convex domains.
Besides an identity result between translative case and lattice case and a general upper bound, exact values for some special
domains are determined. Similar to Mahler and Reinhardt’s result about packing densities, we show that the simultaneous packing
and covering constant of an octagon is larger than that of a circle.
(Received 17 January 2001; in revised form 13 July 2001) 相似文献
59.
Kouichi Akahane Naokatsu Yamamoto Naoki Ohtani 《Physica E: Low-dimensional Systems and Nanostructures》2004,21(2-4):295
We fabricated InAs quantum dots (QDs) with a GaAsSb strain-reducing layer (SRL) on a GaAs(0 0 1) substrate. The wavelength of emission from InAs QD is shown to be controllable by changing the composition and thickness of the SRL. An increase in photoluminescence intensity with increasing compositions of Sb and thickness of the GaAsSb SRL is also seen. The efficiency of radiative recombination was improved under both conditions because the InAs/GaAsSb/GaAs hetero-interface band structure more effectively suppressed carrier escape from the InAs QDs. 相似文献
60.
S. J. Cheng W. Sheng P. Hawrylak S. Raymond S. Studenikin A. Sachrajda Z. Wasilewski A. Babinski M. Potemski G. Ortner M. Bayer 《Physica E: Low-dimensional Systems and Nanostructures》2004,21(2-4):211
We present results of calculations and experiments on electron–hole complexes in InGaAs/GaAs self-assembled quantum dots in high magnetic field (B). Due to hidden symmetries, the chemical potential of an N-exciton system at special B fields becomes insensitive to the exciton number as well as the magnetic field. This results in plateau regions of high intensity in measured magneto-PL spectrum. Theoretical calculations using exact diagonalization techniques successfully explain the measured magneto-photoluminescence spectrum with B fields up to 28 T. 相似文献